Schematic comparison of the thiosulfate (A) and polysulfide (B) mechanisms in (bio)leaching of metal sulfides (Schippers and Sand 1999; Schippers et al. 1996).Iron(III) ions attack metal sulfides (MS) by electron extraction and are thereby reduced to the iron(II) form.As a result, the metal sulfide crystal releases metal cations …
WhatsApp: +86 18221755073The influence of cations, including calcium, sodium, and ammonium, on the leaching of a pyrite concentrate has been studied by Feng and Van Deventer [49], and the results showed that calcium thiosulfate and sodium thiosulfate have the best effect on gold leaching and thiosulfate consumption, respectively.
WhatsApp: +86 18221755073Sodium thiosulfate can be used to leach gold from black sand by creating a solution with the black sand and then adding sodium thiosulfate to dissolve the gold.
WhatsApp: +86 18221755073Thiosulfate leaching has been regarded as a promising alternative to cyanidation, but it still faces the challenge of the recovery of low content of gold from …
WhatsApp: +86 18221755073Designing suitable adsorbents is a key challenge in the recovery of Au(I) from thiosulfate gold-leaching solutions as the ideal adsorbent not only possesses abundant active sites with high affinities and selectivities toward Au(I), but also demonstrates fast recovery of Au(I) at high purity and large capacity. ...
WhatsApp: +86 18221755073The application of pressure oxidation (POX) followed by thiosulfate gold leaching is an efficient method used to extract gold from double refractory gold ores containing both sulfide and carbonaceous matter. This process is expected to result in high gold recovery rates, as it liberates gold from sulfides and eliminates the preg-robbing …
WhatsApp: +86 18221755073AXEL SCHIPPERS* AND WOLFGANG SAND Abteilung Mikrobiologie, Institut fu¨r Allgemeine Botanik, Universita¨t Hamburg, ... (III) ion-mediated leaching mechanism via thiosulfate and polythionates (18 ...
WhatsApp: +86 18221755073Thiosulfate is a lixiviant with potential applications for extraction of precious metals with lower environmental impact. As an alternative leaching reagent to cyanide, thiosulfate has promising gold extraction efficiency with much lower risk to operators and the environment. Thiosulfate is often produced at high temperatures via processes utilizing sulfide or …
WhatsApp: +86 18221755073Thiosulfate is a green gold lixiviant that has promise to replace cyanide at the gold mining industry. Hexaamminecobalt(III) (Co(NH 3) 6 3+) is effective in catalyzing the thiosulfate leaching of gold from ores, but the electrochemical behavior and catalytic leaching mechanisms remain unclear.This paper reports an in-depth investigation into …
WhatsApp: +86 18221755073Compared with the thiosulfate leaching in the presence of inert quartz, the conclusion was obtained that all studied sulfide minerals including chalcopyrite, galena, …
WhatsApp: +86 18221755073Leach compound for gold using sodium thiosulfate on black sand? Updated: 6/8/2024. Wiki User. ∙ 16y ago. Study now. See answers (2) Best Answer. Copy.
WhatsApp: +86 18221755073The ammoniacal thiosulfate leaching process for gold and silver extraction has been reviewed in terms of leaching mechanism, thermodynamics, thiosulfate …
WhatsApp: +86 18221755073The ammoniacal thiosulfate leaching process for gold and silver extraction has been reviewed in terms of leaching mechanism, thermodynamics, thiosulfate stability, and gold recovery options. The application to different ore types and process options have also been discussed.
WhatsApp: +86 18221755073The use of thiosulfate to extract gold from refractory ores is promising because of its non-toxicity and high selectivity. Sulfide minerals (i.e., pyrite, arsenopyrite, chalcopyrite), major gold carriers in refractory gold ores, however, hinder gold extraction due to the high consumption of a lixiviant.
WhatsApp: +86 18221755073@article{osti_318833, title = {Bacterial leaching of metal sulfides proceeds by two indirect mechanisms via thiosulfate or via polysulfides and sulfur}, author = {Schippers, A and Sand, W}, abstractNote = {Bacterial leaching, the biooxidation of metal sulfides to soluble metal sulfates and sulfuric acid, is effected by specialized bacteria. The ...
WhatsApp: +86 18221755073Recent research papers by Ritchie et al. (2001), Nicol and O'Malley, 2001, Nicol and O'Malley, 2002, Aylmore and Muir (2001), Molleman and Dreisinger (2002), Grosse et al. (2003) and Muir and Aylmore (2004) highlighted the potential of the copper(II)–ammonia–thiosulfate system as a noncyanide gold lixiviant for leaching and …
WhatsApp: +86 18221755073Precious metals recovery from secondary sources is a novel alternative since they hold higher contents of several metals than average ores. In this research gold and silver were recovered from Waste Printed Circuit Boards (WPCBs) with the use of ammonia-thiosulfate solutions and the MTA 5011 ion exchange resin.
WhatsApp: +86 18221755073The oxidation of gold in thiosulfate solutions is believed to occur according to Eq. (1).The standard potential for this reaction is 0.15 V (Nicol et al., 1987), and thus dissolved oxygen (E 0 =0.4 V in alkaline solutions; Antelman and Harris, 1982) should oxidise gold to gold thiosulfate.Leaching experiments were performed using the …
WhatsApp: +86 18221755073sand making machine thiosulfate gold from black sand. on sodium thiosulfate leach for gold. thiosulfate leach of gold plateYouTube. Feb 24 2014· recovered powders from a sodium thiosulfate leach of gold plated pins. if all my experiments can be perfected i will have a safe nontoxic process to remove gold from gold plated objects and .
WhatsApp: +86 18221755073This article reviews the thiosulfate leaching of gold, a promising alternative to cyanidation, and discusses the challenges and …
WhatsApp: +86 18221755073The reason for this is uncertain. It can be seen from Figures 11 and 12 that the effect of pH on the copper-thiosulfate reaction is more dramatic than the effect on the gold leaching reaction. Hence thiosulfate leaching should be carried out at pH values above I 1.4 to minimise the consumption ofthiosulfate. 1080 P.L. Breuer and M. 1.
WhatsApp: +86 18221755073The gold in the concentrate calcine was leached with three leaching methods, including thiosulfate leaching, thiourea leaching, and thiourea and thiosulfate leaching. The leaching conditions of gold by thiosulfate were as follows: 5 mmol/L CuSO 4, 0.6 mol/L NH 3, 0.1 mol/L Na 2 S 2 O 3, and leaching time of 12 h [26], and gold …
WhatsApp: +86 18221755073Sodium thiosulfate (0.01 mol) was then added to the Erlenmeyer flask. Next, the Erlenmeyer flask was placed in a constant temperature water bath with a mechanical stirrer set to 25 °C for leaching at 350 rpm for 12 h. Finally, the leached ore pulp was filtered to obtain the Cu–NH 3 –thiosulfate gold-leaching solution. The obtained …
WhatsApp: +86 18221755073Ammoniacal thiosulfate has been studied over the last three decades as a nontoxic and highly-efficient alternative lixiviant to cyanide for leaching gold from gold ores with copper(II) acting as a catalyst [1,2].Much of the work has concentrated on copper-gold ores, carbonaceous gold ores and complex sulfidic gold ores where the recovery of gold …
WhatsApp: +86 18221755073Thiosulfate leaching has been regarded as a promising alternative to cyanidation, but it still faces the challenge of the recovery of low content of gold from high concentrations of thiosulfate solutions. Liquid–liquid extraction is a method to address this issue but is still limited by the use of volatile and toxic organic solvents. To overcome …
WhatsApp: +86 18221755073Under optimized experimental conditions of initial pH 8.50, molar ratio of copper to thiosulfate 0.1 and leaching temperature 313 K, the mercury leaching rate is 92.37% after 7-h leaching. The study on the leaching mechanism indicates that Cu + can be substituted by Hg 2+ to form soluble Hg(S 2 O 3 ) n 2−2n in solution and Cu 2 S …
WhatsApp: +86 18221755073The data indicate that thiosulfate, trithionate, tetrathionates, and disulfane-monosulfonic acid are key intermediate sulfur compounds in oxidative pyrite degradation, and a novel (cyclic) leaching mechanism is proposed which basically is indirect. In the case of pyrite bioleaching by Leptospirillum ferrooxidans, an organism without sulfur-oxidizing …
WhatsApp: +86 18221755073Elemental mercury was used in all leaching experiments. Hydrochloric acid solution was prepared through dilution, and it was used as the pH adjustment solution in hypochlorite leaching experiments. Thiosulfate solution was prepared by dissolving sodium thiosulfate powder (Alfa Aesar Chemical 99% anhydrous) using de-ionized water.
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WhatsApp: +86 18221755073I expect Iron content will have a profound effect on a thiosulfate leach. ... Butcher No problem,I use Thio for leaching ore,and black sand. Once you understand it,the thiosulfate is a fantastic leach. Reply. P. Platdigger Well-known member Supporting Member. Joined Jul 26, 2007 Messages 1,662
WhatsApp: +86 18221755073The positive effect of EDTA on gold leaching has been suggested by Feng et al. [27]. Results show that when EN is substituted for ammonia in gold thiosulfate leaching, thiosulfate consumption is decreased [30, 43]. Furthermore, the addition of EN can also remove the passivation layer, as shown in Fig. 3. However, the effect of EN on …
WhatsApp: +86 18221755073An alternative system to cyanide as a leaching agent is presented for the recovery of gold and silver from cyanicide minerals. These minerals are characterized by the presence of copper and carbonaceous minerals in their composition, therefore increasing both the consumption of reagents and energy requirements for the …
WhatsApp: +86 18221755073Gold leaching using the copper–ethylenediamine–thiosulfate (Cu2+-en-S2O32−) system, which contains copper–ethylenediamine complexes, instead of the use of …
WhatsApp: +86 18221755073Thiosulfate leaching can be effectively improved by a lot of additives including sulfate, sulfite, chloride, phosphate, EDTA, amino acids, guar Gempolym M47, ... After being polished with a 2000 grid sand paper, washed by acetone twice and rinsed with deionized water, gold foil was suspended in the upper part of pulp by a nylon thread in …
WhatsApp: +86 18221755073Download scientific diagram | Schematic comparison of the thiosulfate (A) and polysulfide (B) pathways in (bio)leaching of metal sulfides (from Schippers and Sand (1999), modified). Iron(III) ions ...
WhatsApp: +86 18221755073Reductive precipitation of gold from the pregnant leach liquor using inorganic zinc metal or organic acid is a common process in gold recovery; however, it is not very effective in …
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