It was found that the maximum Ga and Zn leaching efficiencies of 81.22% and 96.72% were obtained at optimum leaching conditions: the leaching temperature of 90°C, the leaching time of 60 min, 3 M H 2 SO 4, the solid-to-liquid ratio of 1:5 (g/mL), and the ultrasound power of 750 W. In all cases, the leaching effect of Zn is not significantly ...
WhatsApp: +86 18221755073lithium in form of slag and dust [9]. Hydrometallurgical methods for recovering valuable metals from LIBs include chemical leaching [10−11] and biological leaching [12−13]. In chemical leaching, reducing agents are used in an acid medium to dissolve the valuable metals. Common acids including inorganic acids (HCl, H 2SO 4 and HNO
WhatsApp: +86 18221755073This work focuses on the leaching of blast furnace (BF) dust under normal conditions of temperature and pressure in dilute sulphuric acid. Leaching experiments were carried out using a solution of ...
WhatsApp: +86 18221755073The leaching residue (mainly Fe 2 O 3) can be used as raw material in the iron-making industry. The flow chart of the technological process is shown in Fig. 1. The iron-rich leaching residue can be utilized to produce high-value materials [34], [35], [36]. Download: Download high-res image (206KB) Download: Download full-size image; Fig. 1.
WhatsApp: +86 18221755073Copper smelting open-circuit (CSO) dust contains various valuable metals, such as copper, lead, and zinc, as well as undesirable toxic elements such as arsenic. Thus, the comprehensive recovery of valuable elements from CSO dust is highly significant from both economic and environmental perspectives. In this review, …
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WhatsApp: +86 18221755073The separation of Cu, Pb, Zn, and As from copper smelting dust through oxidative alkali leaching and sulfide precipitation, as well as the subsequent recovery of As through calcification precipitation and carbothermal reduction, were realized in this study to utilize resources from and safely treat copper smelting dust. The binding behavior of …
WhatsApp: +86 18221755073Zinc oxide dust (ZOD) is an industrial solid waste produced in the production process of wet smelting Zn, with large output and great pollution to the environment. The recycling of metallurgical solid waste such as zinc oxide dust is very important to achieve the sustainable development of the circular economy. An …
WhatsApp: +86 18221755073This study aimed to optimise metal extraction from secondary hazardous sources, such as basic oxygen steelmaking dust (BOS-D). Initially, three batch systems approaches, including bioleaching using Acidithiobacillus ferrooxidans, chemical leaching using choline chloride-ethylene glycol (ChCl-EG) and a combined approach were …
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WhatsApp: +86 18221755073In this paper, water leaching and acid leaching were combined to treat secondary dust of a rotary hearth furnace to achieve zinc enrichment. First, the solubles ZnCl 2, KCl, and NaCl in the dust were dissolved into the water solution through water leaching treatment, and separated from the other insoluble components in the …
WhatsApp: +86 18221755073As a byproduct of lead metallurgy, Cd-As-Pb-bearing dust, is a hazardous waste.This paper proposes a coprecipitation method for Cd and As removal and applies it to dust disposition. First, a thermodynamic analysis of the Cd 2+-AsO 4 3−-H 2 O system was conducted, and the predominant areas of solid phase, including Cd 5 H 2 (AsO 4) 4, …
WhatsApp: +86 18221755073A. Effect of leaching temperature on leaching rate As shown in Fig. 5, the leaching rates for elements, such as Cu, Zn and In, are 80, 75, 35% respectively at 90 °C under atmospheric pressure. Meanwhile, Pb, Bi and Sn can barely be leached. The leaching rates of Cu, Zn and In has been raised dramatically by pressure leaching.
WhatsApp: +86 18221755073Leaching is the key unit operation in metallurgical processes. It is the dissolution of metals from their natural ores into a liquid medium. Leaching processes are classified based on the method used for the leaching of metals, i.e. hydrometallurgy (chemicals) or bio-hydrometallurgy (microbial mediated leaching).
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WhatsApp: +86 18221755073Zn and Ge were selectively extracted from zinc oxide dust (ZOD) by the ultrasonic-H 2 O 2 (UH) combined oxidation-leaching process. In the leaching process, the effects of the dosage of H 2 O 2 (6–29.5 mL), ultrasonic power, initial acidity (100–200 g L −1), liquid/solid mass ratio (4–8 : 1), leaching temperature (50–90 °C), and leaching time (30–240 min) …
WhatsApp: +86 18221755073The As removal ratio reaches 86%, while the Sb leaching ratio is limited to 0.3%, confirming the high selectivity of HNO 3 leaching. The leaching residue is composed of cervantite (Sb 2 O 4) and Sb(III)OHN. By calcining the leaching residue in the air at 200 °C, it can be converted to a mixture of cervantite and valentinite (Sb 2 O 3).
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WhatsApp: +86 18221755073Multi-metal extraction of flue dust from copper smelting is being pursued to meet the increasingly appealing environmental requirements of our modern life. In this paper, the thermodynamic analysis of acid leaching solution was carried out. Ferric arsenate deposits were found in the range of pH = 0–11.63, in the form of FeAsO 4 and …
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WhatsApp: +86 18221755073Li et al. (2015) adopted acid leaching treatments with flue dust as the raw material, but the treatment effect was sub-optimal. Valuable metals were not separated or recovered at high rates. Xing et al. (2014) used sulfuration roasting to treat highly concentrated As-containing Zn dust. The As removal rate was only 70.39%.
WhatsApp: +86 18221755073Crude zinc oxide (C.Z.O.) is one of the important resource of zinc metal extraction. The main source of crude zinc oxide includes: a. zinc dust collected from EAF (electrical arc furnace); b. fume dust collected from zinc leaching residue treatment by waelz kiln; c. zinc fume dust collected from lead slag treatment by fuming furnace; d. zinc skim from steel …
WhatsApp: +86 18221755073A selective removal of arsenic from lead‑antimony-zinc-containing high arsenic dust in NaOH-S system was proposed. • NaOH-S system could solve the problem of high antimony leaching efficiency in the process of arsenic removal in NaOH-Na 2 S system.. 98.17% of Sb, 99.85% of Pb and 99.75% of Zn remained in the leaching …
WhatsApp: +86 18221755073During the disposition of Cd-As-Pb-bearing dust, 84.2% Cd and 69.0% As were leached from the dust via H 2 O-H 2 O 2 leaching, and subsequent Cd and As were satisfactorily removed with precipitation efficiencies higher than 99.7% based on coprecipitation, indicating that the novel method is highly efficient. Moreover, the method …
WhatsApp: +86 18221755073The recovery of metals without generating secondary waste is a critical focus in the management of hazardous copper smelting dust. To tackle the challenges associated with arsenic-containing solid waste and waste acid generated by traditional recycling processes, we propose a two-stage roasting process that prioritizes low-temperature …
WhatsApp: +86 18221755073The technical and environmental aspects of treating electric arc furnace dust (EAFD) using a novel process including alkaline roasting and organic acid leaching were evaluated and compared to the globally applied conventional Waelz process. The global warming potentials of the roasting–organic acid leaching process (with co …
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WhatsApp: +86 18221755073Arsenic is selectively extracted from high-arsenic dust by NaOH–Na 2 S alkaline leaching process. In the leaching arsenic process, the effects of alkali-to-dust ratio, sodium sulfide addition, leaching temperature, leaching time and liquid-to-solid ratio on metals leaching efficiencies were investigated.
WhatsApp: +86 18221755073In this study, we report the recovery of metals from copper smelting dust by oxidation leaching and fractional precipitation technology. Under the optimum conditions, the leaching efficiencies achieved for Cu, As, Fe, Cd, and Zn are 93.4%, 94.2%, 39.7%, 98.1%, and 90.7%, respectively. Fractional precipitation technology is then …
WhatsApp: +86 18221755073Ma AY, Zheng XM, Li S, Wang YH, Zhu S (2018) Zinc recovery from metallurgical slag and dust by coordination leaching in NH 3 –CH 3 COONH 4 –H 2 O system. R Soc Open Sci 5:180660. Article Google Scholar Chen WS, Shen YH, Tsai MS, Chang FC (2011) Removal of chloride from electric arc furnace dust. J Hazard Mater …
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WhatsApp: +86 18221755073The study of copper (Cu) recovery is crucial for the entire recovery process of waste printed circuit boards (WPCBs), and Cu can be leached efficiently via a sulfuric acid–hydrogen peroxide (H2SO4–H2O2) system. To achieve high Cu recovery, it is important to evaluate the parameters of the leaching process and understand the Cu …
WhatsApp: +86 18221755073The paper deals with the extraction of copper from the deposited material of the liner of the electrostatic precipitator (ESP) of the copper smelter plant. These precipitates of ESP liner (ESP dust) generally contain mixed phases of copper and arsenic. An attempt is made to extract copper from ESP dust, subsequently removing arsenic …
WhatsApp: +86 18221755073By using different acidic solvents and leaching conditions to treat the bag dust, the best leaching conditions of K, Na and Zn elements were explored. The results show that the optimal leaching conditions of harmful elements in water solution are: 4 ml/g liquidsolid ratio, 50°C temperature, 30 min stirring time.
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