hemihydrate gypsum, and the influence degree of different forms of soluble phosphorus is unclear. Therefore, the utilization of a-hemihydrate gypsum is greatly limited. In this study, the effect of soluble phosphorus on the setting time and mechanical properties of a-hemihydrate gypsum was investi-gated by adding different amounts of H 3PO 4 ...
WhatsApp: +86 18221755073Dihydrate and β-hemihydrate gypsum exhibit relatively higher solubility and dissolve more quickly than CaSO 4. However, there is little information on their incorporation in CAC. Although Zhang et al. [19] analysed the influence of the type and dosage of calcium sulphate on the properties of CAC-based materials, they did not study …
WhatsApp: +86 18221755073DOI: 10.1016/j.conbuildmat.2024.136656 Corpus ID: 269855858; Preparation of α-calcium sulfate hemihydrate with high mechanical strength from natural fibrous gypsum in KCl-mediated glycerol-water solution
WhatsApp: +86 18221755073DOI: 10.1016/J.FUEL.2016.01.073 Corpus ID: 101524329; Preparation of alpha-calcium sulfate hemihydrate from FGD gypsum in chloride-free Ca(NO3)2 solution under mild conditions
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WhatsApp: +86 18221755073Alpha-calcium sulfate hemihydrate (α-HH) has been prepared from flue gas desulfurization (FGD) gypsum with salt solution method under atmospheric pressure. X-ray diffraction (XRD), thermogravimetry and differential scanning calorimetry (TG-DSC), optical micrograph, X-ray photoelectron spectroscopy (XPS), energy dispersive spectrometry …
WhatsApp: +86 18221755073We are a consortium of the leading natural gypsum producers in the Sultanate of Oman. The member companies have created a synergy between them to cater to the global market. Our Services. Contact us. P.O.Box : 2236, P.C: 211, Salalah, Oman +968 23369555. info@sigoman. About. About me;
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WhatsApp: +86 18221755073thermal analysis in a sample of hemihydrate prepared by calcining gypsum under conditions simulating the manufacture of gypsum plaster in a kettle. By means of differential thermal analysis it is ...
WhatsApp: +86 18221755073The fluidity of hemihydrate gypsum - PCE systems with different F − content is shown in Fig. 5.It was found that in all experiments, regardless of adding PCE or not, F − had a negative effect on the fluidity. This negative effect became more significant as the dosages of F − and PCE increased, while without PCE, it seemed very slight. When the …
WhatsApp: +86 18221755073The synthesis of α-calcium sulfate hemihydrate (α-CSH) from flue gas desulfurization (FGD) gypsum is a good way to realize the comprehensive utilization of FGD gypsum. To obtain α-CSH with the satisfactory performances, a facile hydrothermal-aging pretreatment process for FGD gypsum raw materials was proposed, where FGD …
WhatsApp: +86 18221755073In this study, phosphogypsum (PG) is simulated by doping fluorine and phosphorus ions in an analytically pure reagent of gypsum dihydrate. The influence of fluorine and phosphorus impurity and content on the dehydration reaction process of phosphogypsum and its crystalline micromorphology is assessed during the preparation of α‐type gypsum …
WhatsApp: +86 18221755073Gypsum (calcium sulfate dihydrate) is one of the most used inorganic binding materials in the world. During calcination, calcium sulfate subhydrates are formed and, for technical reasons, are mixed with water …
WhatsApp: +86 18221755073Kelley, Southard and Anderson1 have shown that the thermodynamic properties of calcium sulphate hemihydrate depend on whether the hemihydrate is produced from gypsum calcined in a steam-saturated ...
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WhatsApp: +86 18221755073DOI: 10.1016/j.conbuildmat.2023.130453 Corpus ID: 256217243; Utilization of phosphogypsum to synthesize α-hemihydrate gypsum in H3PO4–H2O solution @article{Chen2023UtilizationOP, title={Utilization of phosphogypsum to synthesize $alpha$-hemihydrate gypsum in H3PO4–H2O solution}, author={Long Chen and Lin …
WhatsApp: +86 18221755073The H 2 O released from gypsum altered one Ca position, which is the reason for the Ca located in two positions in the gypsum structure, although it maintains one position in the prepared HH-CSW structure. Download: Download high-res image (111KB) Download: Download full-size image; Fig. 10. HH-CSW atom-bond formation …
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WhatsApp: +86 18221755073In this article, tricalcium aluminate (C 3 A) was utilized as addition agent for hemihydrate gypsum (HHG) to improve the performance of gypsum pastes, and on that basis, the optimal dosage group of C 3 A was selected for further study on the composite effect with nano-silica (NS). HHG plasters with 0–5% content of C 3 A and besides …
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WhatsApp: +86 18221755073The calcium sulphate dihydrate gypsum (CaSO 4 ·2H 2 O) is the most common sulphate evaporite mineral on our planet 1.Sulphate evaporites play an important role in Earth's sulphur cycle and are ...
WhatsApp: +86 18221755073In this study, phosphogypsum (PG) is simulated by doping fluorine and phosphorus ions in an analytically pure reagent of gypsum dihydrate. The influence of fluorine and phosphorus impurity and content on the dehydration reaction process of phosphogypsum and its crystalline micromorphology is assessed during the preparation …
WhatsApp: +86 18221755073Preparation of α-hemihydrate gypsum (α-HH) from phosphogypsum (PG) by atmospheric hydrothermal method has a good application prospect due to the mild reaction conditions, the solution medium and ...
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WhatsApp: +86 18221755073Phosphogypsum can be used to prepare β-hemihydrate gypsum (β-CaSO 4 ·1/2H 2 O) plaster. A prerequisite for any effective reuse of phosphogypsum is to understanded the act by which impurities in phosphogypsum influence the performance of β-CaSO 4 ·1/2H 2 O plaster, and the role NaF was explored in this study. The results …
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WhatsApp: +86 18221755073The surface modifier was removed using a JY92 − II ultrasonic cell crusher and deionized water. ... Insights into the role of Na(+) on the transformation of gypsum into alpha-hemihydrate whiskers in alcohol-water systems. ACS Omega, 7 (18) (2022), pp. 15570-15579. Crossref View in Scopus Google Scholar
WhatsApp: +86 18221755073The hydration of calcium sulphate hemihydrate (CaSO 4 ·0.5H 2 O) leading to the crystallization of gypsum (calcium sulphate dihydrate – CaSO 4 ·2H 2 O) has been the subject of several investigations over a long period and a vast amount of data is widely distributed throughout in the literature. In this review article an overall picture of the …
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WhatsApp: +86 18221755073Calcium sulfate exists in three forms, namely dihydrate or gypsum (CaSO4·2H2O), anhydrite (CaSO4), and hemihydrate or bassanite (CaSO4·0.5H2O) depending on temperature, pressure, pH, and formation conditions. The formation of calcium sulfates occurs widely in nature and in many engineering settings. Herein, a …
WhatsApp: +86 18221755073An industrially feasible process was proposed to produce α-calcium sulfate hemihydrate (α-HH) from FGD gypsum without any additives. In this process, an AlCl 3 solution was used to promote the conversion of calcium sulfate dihydrate (DH) to hexagonal prismatic α-HH with high strength at atmospheric pressure. The phase transition kinetics …
WhatsApp: +86 18221755073Flue-gas desulphurization (FGD) gypsum is a highly prevalent industrial by-product worldwide, which can be an excellent alternative to natural gypsum due to its high content of CaSO4·2H2O. The preparation of α-calcium sulfate hemihydrate is a high-value pathway for the efficient use of FGD gypsum. Here, a dynamic method, or an improved …
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WhatsApp: +86 18221755073Keywords: α-calcium sulfate hemihydrate, industrial by-product gypsum, FGD gypsum, phosphogypsum, preparation method 1. Introduction 1.1. α-calcium sulfate hemihydrate Calcium sulfate hemihydrate generally exists in two forms, i.e., α- and β-forms. As an important building material, the industrial production and application of β-form began ...
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